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Fluoride series

Penchem 2013. 7. 17. 16:01


 

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Potassium Bifluoride

Molecular formula: KHF2      

Molecular weight: 78.11
Uses: chemical reagent. In producing ceramics, magnesium alloy, anhydrous hydrogen fluoride, pure potassium bifluoride, optical glass, etc.
Properties: white or colorless transparent tetragonal crystal with a little sour odor. It is easily dissolved in the air, slightly soluble in alcohol, easily soluble in cold water. Its solution is strong acidic and is corrosive to glass and ammonium bifluoride, thus it shall be kept in closed plastic container. Specific gravity is 2.37g/mL(25℃), melting point is 239℃.
CAS#: 7789-29-9          Customs No.: 2826199020          MSDS: YF0405-01          IMDG Code: 83004

Potassium bifluoride
Item Standard
Appearance White crystal
Content% ≥99.00%
Free acid % 25.5-25.8
Chloride % ≤0.01
Sulfate % ≤0.02
Fluosilicate% ≤0.01
Heavy metal % ≤0.003
Nickel % ≤0.001
Iron % ≤0.0005
Drying loss% ≤0.20
PH (5% solution)% 3.30-3.50
Whiteness % ≥85.00
Transmittance (15% solution)% ≥99.00

Notes: special specifications can be produced at the request of customers.

 

 

 

Strontium Fluoride

Molecular formula: SrF2
Molecular weight: 125.63  
Uses: in producing optical glass and single crystal for laser; in pharmaceutical industry and daily chemical industry, such as caries prevention additive of toothpaste, high-ranking electronic components; in pharmaceutical and other substitutes of fluorides.  
Properties: White colorless cubic crystalline powder, slightly soluble in water, soluble in hydrochloric acid, insoluble in hydrofluoric acid, ethyl alcohol and acetone. It is stable in the air. Density is 4.24, melting point is 1473℃, boiling point is 2489℃. It turns into strontium oxide at temperature above 1000℃ in the air.
CAS#: 7783-48-4Customs No.: 2826199090  MSDS:   IMDG Code:  

Specifications High-purity grade Export grade Industrial grade
Standard SEMI C1 Mint Standard Mint Standard
Appearance White colorless cubic crystalline powder White colorless cubic crystalline powder White colorless cubic crystalline powder
Content    % ≥99.9 ≥99.0 ≥98.5
Strontium oxide (SrO)% 79.5-81.5    
Fluorine (F)ppm 29.0-30.5    
Chloride (Cl)pm ≤5 ≤50 ≤500
Sulfate (SO42-)  pm ≤10 ≤100 ≤1000
Sodium (Na)pm ≤1 ≤10 ≤100
Iron (Fe)pm ≤1 ≤10 ≤100
Lead (Pb)ppm ≤2 ≤20 ≤200
Arsenic (As)ppm    ≤1 ≤10 ≤100
Heavy metal (Pb)   pm ≤5 ≤200 ≤2000
Barium fluoride (BaF2)   pm ≤12000    
Sulfur (S)pm ≤100    
Phosphorus (P)pm ≤20    
Cadmium (Cd)ppm ≤1    
Tin (Sn)ppm ≤100    
Carbon dioxide (CO2) pm ≤200    
Chromium (Cr)ppm ≤5    
Mercury (Hg)ppm ≤10    
Calcium (Ca)  % ≤1    
Cobalt (Co)ppm ≤5    
Copper (Cu)ppm ≤2    
Manganese (Mn)ppm ≤2    
Nickel (Ni)pm ≤5    
Loss on ignition (500℃)  % ≤3    
Moisture (105℃, 2h)ppm      
PH (50g/L,25℃)      
Supply reference
Particle size      
Transmittance      
Packing 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL
Quotation specifications full container full container full container
Quotation reference yuan/ton      
Valid period of the offer Three months Three months Three months

Notes: special specifications can be produced at the request of customers.

 

 

Barium Fluoride

Molecular formula: BaF2
Molecular weight: 175.32
Properties: Colorless transparent cubic crystal or white powder. Soluble in hydrochloric acid, nitric acid, hydrofluoric acid and ammonium chloride solution, as well as methyl alcohol, ethyl alcohol and other organic solvents, slightly soluble in water, relative density is 4.83. Melting point is 1368℃, boiling point is 2260℃, refractive index (n25D) is 1.471. Median lethal dose (rat, per os) is 250mG/kG.
Uses: in producing motor brush, optical glass, light-guide fibre, laser generator, flux, coating enamel; as wood preservative, pesticide, corpse preservative, solid lubricant, etc.
CAS#: 7787-32-8         Customs No.: 2826199090      MSDS:     IMDG Code:  

Specifications Electronic grade Export grade Industrial grade
Standard SEMI C1 Yotech Standard Yotech Standard
Appearance Colorless transparent cubic crystal or white powder Colorless transparent cubic crystal or white powder Colorless transparent cubic crystal or white powder
Content% ≥99.99 ≥99.0 ≥98.5
Chloride (Cl)  pm ≤10 ≤100 ≤500
Sulfate (SO42-)  pm ≤10 ≤100 ≤500
Free acid (HF)  pm ≤200    
Lead (Pb) ppm ≤1 ≤10 ≤100
Arsenic (As)ppm    ≤1 ≤1 ≤10
Sulfur (S) ppm ≤1 ≤10 ≤100
Phosphorus (P)  m ≤15 ≤15 ≤150
Heavy metal (Pb) ppm ≤5 ≤5 ≤50
Silicon dioxide (SiO2)pm ≤20 ≤2000 ≤5000
Sodium (Na)  ppm ≤1 ≤10 ≤100
Iron (Fe)  ppm ≤1 ≤10 ≤100
Magnesium (Mg)ppm ≤10    
Manganese (Mn)ppm ≤10    
Copper (Cu) ppm ≤10    
Cobalt (Co) ppm ≤10    
Chromium (Cr) ppm ≤10    
Strontium (Sr) ppm ≤10000    
Mercury (Hg) ppm ≤10    
Nickel (Ni) ppm ≤10    
Moisture (105℃, 2h)    ppm ≤1000 ≤1500 ≤3000
PH (50g/L,25℃)      
Supply reference
Particle size 90% pass 110 mesh 90% pass 110 mesh 90% pass 110 mesh
Transmittance      
Packing 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL
Quotation specifications full container full container full container
Quotation referenceyuan/ton      
Valid period of the offer Three months Three months Three months

 

 

 

 

Sodium Fluoride

Molecular formula: NaF Molecular weight: 41.99
Uses: aluminium smelting and welding flux, medical and wood preservative, fungicide in brewing industry, agricultural pesticide, fluoridation agent of drinking water. It cna also be used in papermaking, toothpaste production, chemical reagent, acid pickling of strip steel and stainless steel, raw material of other fluorides, adhesive. In addition, it is also used in enamel and pharmaceutial industries.
Properties: colorless bright crystal or white powder. Soluble in water, slightly soluble in alochol. Its solution presents alkaline and is corrosive to glass. Soluble in hydrofluoric acid and generates sodium hydrogenfluoride. Specific gravity is 1.02g/mL(20℃), melting point is 993℃, boiling point is 1700℃.
CAS#: 7681-49-4 Customs No.: 2826192010 MSDS: YK16-06 IMDG Code: 61513

Sodium fluoride
Item Standard
Appearance White powder
Content ≥99.50
Water insoluble matter % ≤0.05
Silicon dioxide % ≤0.01
Sulfate % ≤0.005
Acidity mmol/100g ≤10.0
Alkalinity mmol/100g ≤5.0
Drying loss % ≤0.2
Fluosilicate % Conform to test
Chloride % ≤0.012
Heavy metal % ≤0.0005
Whiteness % ≥95
Transmittance % ≥90
Particle size 100-300 mesh

Notes: special specifications can be produced at the request of customers.

 

 

Ammonium Bifluoride

Molecular formula: NH4HF2 Molecular weight: 57.04
Uses: the product can be used in the treatment of electronic products such as LCD TVs; in glass etchants with hydrofluoric acid; disinfectant and preservative in fermentation industry; in producing ceramics, magnesium alloy; as analytical reagent and bacteria inhibitor; solvent of metal beryllium; surfactant of silicon steel plate.
Properties: Ammonium bifluoride is corrosive chemical. Molecular formula is NH4HF2. Its solution presents weak alkali. It can dissolve glass, slightly soluble in alcohol, easily soluble in cold water. White or colorless transparent orthorhombic crystal with a little sour odor. It is toxic!
CAS#: 1341-49-7 Customs No.: 2826191010 MSDS: YF0405-06 IMDG Code: 83003

Ammonium bifluoride
Item Standard
Appearance White crystal
Content % ≥99.00%
Drying loss % ≤0.5
Loss on ignition % ≤0.05
Chloride (Cl) % ≤0.01
Sulfate (SO42-)% ≤0.01
Ammonium fluosilicate (K2SiF6) % ≤0.5
Heavy metal % ≤0.003
Iron (Fe) % ≤0.005

Notes: special specifications can be produced at the request of customers.

 

 

Potassium Fluoride

Molecular formula: KF          Molecular weight: 58.10
Uses: Mainly used for all kinds of metal, alloy welding flux, widely used as a fluorinating agent in organic compounds in the production, for the production of sodium fluoroacetate and agricultural insecticide fluoroacetamide medicine, used for norfloxacin, it can be used as absorbent (HF and water), it is also preparing potassium hydrogen fluoride materials, also can be used for glass carving and food preservation and the application in the electronics industry.
Properties:Colorless cubic crystal, easy deliquescence, soluble in water, soluble in hydrofluoric acid and ammonia, slightly soluble in alcohol and acetone, the aqueous alkaline reaction, the corrosion of glass and ceramics, only a little heated to decomposition sublimation temperature, but the molten potassium fluoride activity greatly, can corrode the refractory matter. Toxic and should be stored airtight. Specific gravity 2.48, melting point 858 DEG C.
CAS#:7778-23-3          Customs number:28261900          MSDS:YF0405-02          Dangerous regulation number:61513

Potassium fluoride (crystallization)
Product specification Crystal
Implementation standards YingKe
content% ≥99.0
Water content(105℃,2h),% ≤0.15
loi(500℃,2h)% ≤0.5
Free acid(HF),% ≤0.2
Free alkali(KOH),% ≤0.2
chloride(Cl),% ≤0.005
pH(50g/L) 7—8.5
iron(Fe),% ≤0.0005
silicon(SiO2),% ≤0.001
granularity 20-50
sulfate(SO4),% ≤0.002
phosphate(PO4),% ≤0.0005
Total carbon(C),% ≤0.002
Water insoluble matter,% ≤0.01
calcium(Ca),% ≤0.0005
chromium(Cr),% ≤0.0001
magnesium(Mg),% ≤0.0005
sodium(Na),% ≤0.1
nickel(Ni),% ≤0.0001
phosphorus(P),% ≤0.0002

 

Potassium fluoride (industrial spray)
Product specification 喷雾
Implementation standards YingKe
content,% ≥99.0
Water content(105℃,2h),% ≤0.1
Free acid(HF),% ≤0.2
Free alkali(KOH),% ≤0.2
chloride(Cl),% ≤0.001
pH(5%) 7—8.5
iron(Fe),% ≤0.0005
silicon(SiO2),% ≤0.005
Grain size (95 through) 250-500
sulfate(SO4),% ≤0.02
phosphate(PO4),% ≤0.005
Water insoluble matter,% ≤0.01
sodium(Na),% ≤0.1

Notes: special specifications can be produced at the request of customers. 

 

 

Magnesium Fluoride

Molecular formula: MgF2 Molecular weight: 62.3
Uses: optical lens coating; ceramic and electronic industries; in producing ceramics and glass; smelting flux of magnesium metal; fluorescent material of cathode ray screen, flux, etc.
Properties: Colorless crystal or white powder. Rutile type lattice with a little violet fluorescence. Very slightly soluble in water (18℃, 87mG/L), slightly soluble in dilute acid (particularly nitrate). Relative density is 3.18, melting point is 1248℃, boiling point is 2260℃. Lethal dose (guinea pig, per os) is 1.0G/kG. Irritant.
CAS#: 7783-40-6    Customs No.:    MSDS:    IMDG Code:

Specifications High-purity grade Export grade Industrial grade
Standard SEMI C1 Mint Standard Mint Standard
Appearance Colorless or white crystal Colorless or white crystal Colorless or white crystal
Content ≥99.9 ≥99.0 ≥98.5
Chloride (Cl)ppm ≤10 ≤10 ≤100
Sulfate (SO42-)ppm ≤10 ≤10 ≤50
Sodium (Na)ppm ≤10 ≤10 ≤100
Iron (Fe)ppm ≤1 ≤10 ≤50
Arsenic (As) ppm ≤1 ≤1 ≤10
Heavy metal (Pb)ppm ≤20 ≤20 ≤200
Magnesium oxide (MgO) % ≤1.5
Phosphorus (P)ppm ≤60
Sulfur (S)ppm ≤110
Nickel (Ni)ppm ≤30
Copper (Cu) ppm ≤20
Zinc (Zn) ppm ≤50
Strontium (Sr)ppm ≤10
Yttrium (Y)ppm ≤20
Manganese (Mn)ppm ≤50
Aluminum (Al)ppm ≤820
Silicon (Si)ppm ≤520
Calcium (Ca) % ≤0.295
Moisture (105℃, 2h)ppm ≤0.5 ≤1.0 ≤1.5
PH (50g/L,25℃)
Supply reference
Particle size 30-100 mesh pass 98% 325 mesh pass 95% 60-220 mesh pass 95%
Transmittance ≥90 ≥90 ≥90
Packing 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL 25KG composite bag/16T/(20’)FCL
Quotation specifications full container full container full container
Quotation reference yuan/ton

 

 

Calcium Fluoride

Molecular formula: CaF         Molecular weight: 78.07
Uses: in producing hydrofluoric acid. Pure product can be used as catalyst of dehydration and dehydrogenation reactions. Smelting flux. Optical glass. Polishing paste of electronic materials.
Properties:  White powder or cubic crystal. Soluble in concentrated inorganic acid and gives off hydrogen fluoride, slightly soluble in dilute inorganic acid, almost insoluble in water. Relative density is 3.18, melting point is 1402℃, boiling point is 2500℃. Median lethal dose (rat, per os) is 2775mg/kg.  
CAS#: 7789-75-5        Customs No.: 252910000     MSDS:   IMDG Code:  

Specifications Electronic grade Export grade Industrial grade
Standard SEMI C1 Mint Standard Mint Standard
Content   % ≥99.9 ≥99.0 ≥98.5
Calcium (CaO)           % 70-72    
Fluorine (F) % 47.5-49    
Calcium carbonate (CaCO3)     % ≤0.5    
Chloride (Cl)         ppm ≤10 ≤10 ≤100
Sulfate (SO42-)      ppm ≤10 ≤10 ≤100
Sodium (Na)             ppm ≤10 ≤10 ≤100
Iron (Fe)             ppm ≤10 ≤10 ≤100
Lead (Pb)            ppm ≤10 ≤10 ≤100
Arsenic (As)            ppm    ≤1 ≤1 ≤10
Silicon (Si)             ppm ≤1 ≤1 ≤10
Chromium (Cr)             ppm ≤2    
Cobalt (Co)            ppm ≤1    
Copper (Cu)            ppm ≤1    
Vanadium (V)             ppm ≤1    
Nickel (Ni)             ppm ≤5    
Nickel (Ni)             ppm ≤5    
Heavy metal (Pb)         ppm    ≤5 ≤5 ≤50
Magnesium (Mg)            ppm ≤500    
Sulfur (S)ppm ≤200    
Phosphorus (P)ppm ≤200    
Insoluble matter in hydrochloric acid         ppm ≤10 ≤10 ≤100
Loss on ignition (500℃, 2h)   % ≤5000    
PH (50g/L,25℃)      
Center control inspection
Appearance identification Colorless crystal or white powder Colorless crystal or white powder Colorless crystal or white powder
Drying loss (105℃/2H)  % ≤1.0 ≤1.5 ≤2.0
Transmittance (15%)         % 99.5%    
Whiteness (70-90umParticle size )   %      
Particle size (U.S.SCREEN)   mesh 90% pass 110 mesh    
Shelf life Two years Two years Two years